![]() ![]() ![]() ![]() For additional ideas, check out our roundups of the best Halloween costume ideas for women, work-appropriate Halloween costumes, plus-size costumes, and family Halloween costumes. If you plan to celebrate Halloween all weekend long, you might need more than one costume on hand. We've included links so you can shop for some of the basic materials online, then get crafty at home to really make these outfits your own. If you enjoy the creative process of making your own costumes (date night, anyone?), these ideas are a great jumping off point. Many of these costumes can be purchased online as a complete set, so you can simply order now and put them aside until the fall. Admit it, sharing the same-themed costume with your besties is much more fun than being a. There are Disney couples costumes, punny costumes, plus-size couple costumes, and costumes that can be added to for trios or larger groups. Best friend Halloween costumes are totally a thing right now. Our list of the best couples Halloween costumes has all of the inspiration you need, whether you're a duo known for your scary couple Halloween costumes, you want to emulate one of the hottest celebrity couples of 2023, or you're looking for the best pop culture costumes for pairs. Especially when planning couples costumes - meaning you and your partner will need to agree on a Halloween costume idea that suits both of your personalities - getting a head start ensures you'll have plenty of time to create the perfect look for October 31. Halloween may be months away, but if you're serious about spooky season, it's never too early to begin brainstorming costume ideas. ![]()
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![]() New Urbanism is famous for combining pedestrian friendly neighborhoods with a thriving mixture of job and housing opportunities. It is also noted as an attractive representation of the urban design movement known as New Urbanism. Luxury Apartment Living In Historic Quincy MA The neighborhood of Marina Bay has been cited by the state of Massachusetts as a flourishing example of traditional neighborhood development. The Bay itself is home to a marina with 685 slips and a bustling boardwalk. 2,299 1 Available Unit S3 Studio, 1 Bath 475 sq. Metro Marina Bay luxury apartments fit right in. Metro Marina Bay 7 Seaport Drive, Quincy, MA 02171 (28 Reviews) 2,299 - 3,699/mo Share Feedback Write a Review Leave a Video Review New View Community Timeline Floor Plans & Pricing All (15) Studio (3) 1 Bed (6) 2 Beds (6) Studio S2 Studio, 1 Bath 500 sq. It is also home to a vibrant and educated population. Look forward to permanently living at a luxury hotel! Apartments in Quincy MA 02171 Metro Marina Bay: Luxury Living In Quincy MA Quincy is a city that's part of the greater Boston community and is rich in American history. There is dry cleaning pick up at the building and there are dog walkers that come visit daily as we are a pet friendly community. In our common areas, we have a Club Room, Fitness Facility, Business Center and indoor garage parking. Metro Marina Bay in Quincy, MA 02171 See official prices, pictures, amenities, 3D Tours, and more for Studio to 2 Bedroom rentals from 2299 at Metro Marina Bay on. Every apartment has a private balcony and a washer and dryer. ![]() All of our floor plans offer spacious closets and most have soaking tubs. Inside the apartments we offer gas heat, forced hot air and central air conditioning. There is a complementary shuttle available from our community that brings you to the Red Line every 15 minutes from 6am- 11 pm on weekdays! The property is located on 6 acres of beautifully landscaped grounds. Our apartment homes offer sweeping views of the Boston skyline or the Bay. This picturesque harbor side community offers our residents an extravagant lifestyle with an elegant address. To learn why you should have representation in every real estate transaction, click here.Metro Marina Bay is a luxury apartment community located in the heart of Quincy's popular Marina Bay, just a short stroll away from the boardwalk that is famous for its quaint shops, waterfront dining, nightlife, and breathtaking sunsets. Elevated provides tenant representation only, at no charge where applicable. For tenant representation, contact Elevated Realty today.Įlevated Realty is not associated with the developer or leasing team at Meriel Marina Bay. The building is currently paying broker fees and offering one month free on most units for a limited time. Displaying listings near Marina Bay - Quincy, MA. Leasing at Meriel Marina Bay is underway. Your search did not match any properties, but here are some nearby. Ideally located in desirable Marina Bay, these waterfront units will have unparalleled views of the Boston skyline as well as a plethora of amenities on site. This pet-friendly building will boast three elevated outdoor courtyards, a swimming pool and a fitness center. Units will be a mix of studio, 1 bed, 2 bed, 3 bed and 4 bed townhouse floor plans. ![]() Meriel Marina Bay, located at the former Ocean Club site on Marina Bay's waterfront, will have 352 luxury apartments, 500 parking spaces (garage, $50/month) and 20,000 square feet of retail. ![]() ![]() ![]() The audience only sees as much as she allows. She is the narrator of her own life and this is her world that we’re peeking into. And this device is introduced right away in the pilot, setting the tone for the entire series.įleabag uses her eye contact and comments to the camera as a way to invite the audience in. The show has been praised for its original use of the age-old technique of breaking the fourth wall. Fleabag: Episode 1Ĭreator and star of Fleabag, Phoebe Waller-Bridge, gives us a series about a charming and cynical thirty-something navigating her life. Midge’s expectations have been upended and we await to see how she will react. How is she going to react? The end of the pilot leaves the story in a very contrasting place to how it was at the beginning. We find Midge in a certain place in her life, only for that certainty to be upended. The pilot for this series shows how to balance contrast and expectations. Midge wants to fit in the nuclear family mould, but she needs to follow the journey that her newly found talent might take her. All the characters have defined personalities that make for dynamic relationships and entertaining interactions. The realistic world of 1950’s New York is set up right away with the vintage, authentic costuming and the richly detailed and lavish setting. On the surface, she has it all, but after the inciting incident of her husband leaving her, her lavish lifestyle seems deeply flawed. This is the Midge that viewers want to tune in for every episode. In a drunken state, Midge stumbles on stage and shows off her full-blown talent as a stand-up comedian. Midge’s husband leaves her for his pencil-pushing assistant and life as she knows it falls apart. Fast forward four years and the Maisels’ perfect marriage seems as strong as ever. The pilot begins on Midge Maisel’s wedding day where we get the first glimpse of her natural performative humor with her speech. Maisel, Rachel Brosnahan plays the perfect 1950’s housewife, who comes from a wealthy Jewish family from New York’s Upper West Side. In Amy Sherman-Palladino’s The Marvelous Mrs. ![]() These are TV pilots that not only got their series’ off the ground but also stand up as brilliant episodes of television in their own right. ![]() The question is, how do you implement these elements in the most effective way possible? Well, the best way to learn is to look at how some of the greatest TV pilots successfully kicked off their series. It should establish the pace, tone and stakes of the forthcoming series and, most importantly, leave the audience wanting more. Secondly, it should set up character relationships and their personal wants/needs. First and foremost, it should introduce the audience to a new world and the characters that inhabit it. The TV pilot is the introduction to a series. To help relieve some of that added pressure, let’s go over some essentials your pilot needs. ![]() The truth is, your series won’t even make it into a pitch session, let alone onto the small screen, if your pilot falls short in any way. Or well-written pilots that get cancelled after a single season, i.e. Sure, there have been less than perfect pilots that go on to be wildly popular series, i.e. The difference between a failed pilot and a successful one is the potential outcome of the entire series. Understanding the importance, function and objective of a TV pilot are the first steps to writing a great one. The Mary Tyler Moore Show: Love Is All Around ![]() ![]() ![]() Due to followers not participating in any interaction, it would make an account look spammy or disingenuous. In other words, accounts are ‘purchasing’ followers, hoping this will boost their profile. Those who oppose this tactic believe it is not organic growth, as users do not willingly follow accounts. A key question is whether the methods used involve human interaction or bot automation, and if the latter, whether that is an acceptable practice. While some may think it’s an easy step to gain more traction on the platform. Many people believe it is unsanctioned or an illegitimate way to obtain followers. The idea of obtaining free Instagram followers instantly is a topic that needs to be discussed. The number of followers an account has can be seen as a measure of its popularity or influence within its niche target audience. They want to stay updated with your posts and what you share. ![]() When someone follows you on Instagram, they’re interested in what you have to say. ![]() Instagram followers are users who have chosen to follow your account in order to see your content regularly in their feed. You can reap the benefits of increased visibility and engagement on Instagram by having more followers, which we will discuss. Gaining supporters is key to developing your arrival on this online media stage. In today’s digital age, Instagram has become a powerful platform for individuals and businesses to connect with their audience, showcase their work, and grow their brands. It is important to look at all perspectives before deciding if automation or legitimacy should be prioritized when acquiring free Instagram followers. Some argue it is not organic growth, while others think it can increase engagement and brand awareness. The debate to instantly obtain free Instagram followers is controversial and complex. They use various services that claim to be 100% secure and safe, often promoting their services through ads. However, some may opt for a fast, cheap, guaranteed way to buy followers. A better solution may be to find ways to organically increase your following, such as engaging with other users, watching and sharing videos, and using relevant hashtags. Get ready because you don’t want to miss out on today’s latest tips to becoming an Instagram sensation! Quick Overviewįor some, there is no way to legitimately get free Instagram followers without breaking the site’s terms and conditions. So, if you want to boost your online profile, this is a must-read piece. We’ll also discuss various trial packages and services different businesses offer for their products and a list of things to consider. We’ll cover why gaining followers is essential, how to get them, and which programs and services are the most reliable. In this ultimate guide, we’ll show you the quick and easy steps to get free Instagram followers instantly. Thanks to app development and technological advances, that dream is now a reality. Is there any better way to bolster your digital presence and showcase your views to friends, strangers, or even the world? But what if there were a way to instantly get thousands of free Instagram followers by entering your username and undergoing verification? A feature that even offers a YouTube tutorial video on their site? Well, that’s the dream many seek to achieve, and in this article, we’ll dive into the details of such services offered by various companies. When increasing your social clout, nothing packs the same punch as an Instagram following. ![]() Get Free Instagram Followers Instantly - The Ultimate Guide ![]() ![]() ![]() ![]() We offer nationwide delivery on all of our new and used RVs and have proudly served campers from West Virginia, Ohio, and other great states! If you're near New York, Pennsylvania, New Jersey, Connecticut, Massachusetts, or Maryland, come visit one of our 12 locations today and experience the difference with Meyer's RV Superstores. Meyer's RV is the largest family owned and operated dealer in the Northeast with over 180 years of combined experience. Head on over to our Camper Connect page to check out a detailed overview of some of our top RVs! With our high-volume buying power we are able to deliver you the lowest national pricing on all our inventory. 2021 Winnebago Solis Silverado is a 2021 Winnebago Solis Class B with a very convenient pop-top in addition to the lower level full size Murphy bed, allowing for up to 4 full sized travelers. ![]() We have the largest selection of inventory with over 100 brands from 12 of the industry's top manufacturers. Solis 59px comes with 4 seats and a pop top what allow 4 adults of kids to sleep comfortably. Welcome to Rove Vans We love the great outdoors, so we have made it easier than ever for you to explore them with friends and family. Here is Red Van, travel anywhere, park anywhere on this amazing Winnebago Solis with a top of amenities and customizations to make your travel unforgettable. We are proud to carry the most popular RV manufacturers and brands, including Forest River, Grand Design, Heartland, Jayco, Keystone RV, Prime Time, Starcraft, Thor Motor Coach, Winnebago, East to West, Alliance, Coachmen RV Rockwood, and many more! We carry a wide range of RV types / classes in our inventory, such as Class A Motorhomes, Class B Motorhomes, Class C Motorhomes, travel trailers, fifth wheels, hybrid travel trailers, park models and more! Be sure to visit for all of our boat and marine inventory! New 2021 Winnebago Solis - Seats 6, Sleeps 4, Kid-Friendly - Rove Vans. If you like this video please give it a thumbs up, leave comments, and please consider subscribing to stay up to date on. See prices, photos and find dealers near you. The versatile Solis Pocket ®, Winnebagos most affordable camper van, lets you pursue outdoor adventures of all kinds. Welcome to Meyer's RV Superstores, with convenient locations in New York, Pennsylvania, New Jersey, Ohio, and Maryland – Albany, NY, Rochester, NY, Farmington, NY, Bath, NY, Syracuse, NY, Caledonia, NY, Webster, NY, Harrisburg, PA, Pittsburgh, PA, Mt Morris, PA, Branchville, NJ, Madison, OH, and Joppa, MD. Find new and used Winnebago Solis RVs for sale near you by RV dealers and private sellers on RVs on Autotrader. ![]() ![]() ![]() Unsurprisingly, being a Chelsea fan, Scofield also mocks Arsenal with, “And I haven’t had a trophy in a long time/Must have thought that I played for the Gunners.” With lines like that, there’s no way we couldn’t include this track (sorry, Arsenal fans). Stretch It is packed full of football references: Arshavin’s four goals in Arsenal’s 4-4 draw with Liverpool in 2009, Kante’s tireless work rate and Mbappe’s move from Monaco to PSG are all cited in what will surely be remembered as one of the best FIFA soundtrack songs of the 2020s. Search more than 600,000 icons for Web & Desktop here. But our vote goes to Leicester’s finest, JB Scofield. Fifa online 2 Icons - Download 146 Free Fifa online 2 icons IconArchive. FIFA Sound Music from the FIFA World Cup Qatar 2022 Official Soundtrack Trinidad Cardona, Davido, AISHA 3:26 4 Arhbo (feat. FIFA Sound) Official FIFA Fan Festival Anthem Nicki Minaj, Maluma, Myriam Fares 2:58 3 Hayya Hayya (Better Together) feat. A VFX house shrunk down the players in a D&D game, placed them on the table, and then filmed them kicking ass. There are various modes for you to try and a great number of events running in the game regularly. ![]() 11: JB Scofield: Stretch It (FIFA 20)įIFA 20 had a very strong soundtrack, with bangers coming from the likes of Friedberg, Kamakaze x Massappeals (featuring Morgan Munroe and Foals). The Official FIFA World Cup Qatar 2022 Theme FIFA Sound 1:52 2 Tukoh Taka (feat. Way to go Try different modes and rise in the leaderboards So what can you do with all these great guys You can combine them into teams and send them to the stadium to struggle for the title of the champions. To celebrate the release of the latest instalment in the world’s biggest football game series, here is a starting 11 for the best FIFA soundtrack songs in the game’s history. Each year the game seems to be on point with its music selection, and hopefully FIFA 21 won’t be an exception. Mode (s) Single-player, multiplayer, online multiplayer. Southeast Asia gaming revenue will double to 1 billion by 2015. Early access for FIFA 23 Ultimate Edition begins on September 27, 2022.Whether it’s scrolling through countless numbers of cards to buy on Ultimate Team, playing with Wayne Rooney in the arena or watching the star-studded video intro of Ronaldinho, Thierry Henry and Alessandro Del Piero in FIFA Football 2004, music is at the heart of everyone’s experience playing FIFA. Malaysia International Game Show set for this weekend. Players who pre-order the Ultimate Edition of FIFA 23 or are subscribed to EA Play will be given early access to the game, allowing players access to the game on Tuesday, September 27, 2022.įIFA 23 is developed by EA Vancouver and EA Romania and will be available worldwide on PlayStation 5, Xbox Series X|S, PC, Stadia, PS4, and Xbox One on September 30. The all-new soundtrack to FIFA 21 featuring tracks by more than 100 artists from 23 different countries now defines global culture like never before. What do you make of the most popular FIFA songs of all-time list? And, have we missed any out? Let us know in the comments!įIFA 23 will be released on Friday, Septemfor PlayStation 5, Xbox Series X, Xbox Series S, PC, Stadia, PS4, and Xbox One. The popular Australian artist has become something of an indie. ![]() ![]() The oldest song on the list is Blur's 'Song 2', featuring in FIFA 1998. If you have never listened to Vance Joys stuff before, your time has come. Heatwaves featured on FIFA 21, and the song reached number five on the UK Singles Chart and number one in countries such as Australia, Canada and the United States.ġ4 of the 20 most streamed songs were from the 2010s, with FIFA 15 and FIFA 19 both having three songs on the list. FIFA Online 2 gratis 8,5 270 Conquista la corona di miglior giocatore di calcio del pianeta con FIFA Online. Heatwaves by Glass Animals is the most streamed FIFA song of all time, with the song very close to being streamed almost two billion times as of September 2022. ![]() ![]() ![]() We get into this state of coherence when we shift our emotional state thus achieving heart-brain coherence which helps to calm your mind. This is what we successfully teach our clients to do for themselves. (heartmath) on Instagram: What is heart coherence Heart coherence is when the heart and mind are aligned and. When our heart sends coherent signals to the brain, the brain synchronizes to the heart’s coherent rhythm. Our mind, body and heart are meant to work together. The Heart Math Institute has over 20 years of peer reviewed research, demonstrating the power of training a wide cross section of people with tools and techniques to entrain physiological and emotions coherence and resilience. We do this through evidence based programs created by HeartMath™. Simply stated, if our body and brain work better, we feel and perform better. ![]() ![]() Research also shows that when we activate this state our body functions more efficiently, we experience greater emotional stability, and we have increased mental clarity. During a coherent heart rhythm, the activity in the two branches of the autonomic nervous system ANS is synchronized. Here are some ways to cultivate and remain coherent through practice and spiritual study: Meditation: Regular meditation helps quiet the mind, deepen self-awareness, and foster a sense of inner peace. To fully comprehend heart and brain coherence, it is vital to first understand the autonomic nervous system. This state is associated with feelings of well-being, relaxation, and improved cognitive function. This coherence has been linked to a sense of wellbeing both physical and emotional. Combined with a healthy diet and regular exercise, the primary method to achieve heart-brain coherence is a simple 10-second breathing technique. Cultivating and maintaining mind-heart coherence involves practices that promote mental and emotional balance, self-awareness, and inner harmony. Heart coherence is a state in which the heart, mind, and emotions are synchronized and balanced. The frequency for this optimal state is approximately 0.10 Hertz. This state is called psychophysiological coherence, which involves increased order and harmony in both our psychological (mental and emotional) and physiological (bodily) processes. When we experience uplifting emotions such as appreciation, joy, care, and love our heart rhythm becomes more coherent or consistent. When the heart, brain, and breath are all synced, coherence is optimal. Research has shown that training a person to access coherent HRV patterns prompts a bodywide shift to a specific, scientifically measurable state. We can experience an overall feeling of connectedness when we access our heart’s intelligence, and accessing it also has immediate, tangible benefits. Conversely, coherent HRV and positive emotions correlate with optimum health, well-being and the ability to adapt to stress. The heart serves as a source for feelings of wholeness while also allowing us to experience positive emotions, such as joy, love, and gratitude. ![]() ![]() ![]() Given the vector P = (2, 4), determine the negative of P.īy definition, the negative of a vector has the same magnitude as the reference vector’s opposite direction. We will then discuss some more examples and their step-by-step solutions to develop an even deeper understanding of negative vectors. This section will first consider different examples where we find negative vectors by comparing the reference vector’s components. Remember that the magnitude of vector – X is the same as that of vector X. ![]() To obtain X’s negative vector, we multiply X by -1, making it – X. Two such vectors will be the negative vectors of each other.įinding the negative vector of a given vector can be done by placing a negative sign in front of it. The basic idea behind finding the negative vector of a given vector is to find the two components of the given vector (i.e., the vector’s magnitude and the direction) and then find a vector of the same length that points in the opposite direction. This criterion is enough to show that B is the negative vector of A and vice versa. We say that the vector B is the negative of vector A, or: For example, consider the vectors A = (ax1, ay1) and B = (bx1, by1). If the vectors’ coordinates are equal in value but have opposite signs, the vectors will be the negatives of each other. Mathematically, we can say that two vectors A and B are the negatives of each other if they satisfy the following two conditions:Ī = – B (“Vector B is negative of vector A”)Ī ↑ and B ↓ or A↓ and B ↑ (Opposite directions).Īnother simple method to find out if two vectors are the negatives of each other is to compare their coordinates. The negative sign is used here to indicate that the vector has the opposite direction of the reference vector. The magnitude, or length, of a vector, cannot be negative it can be either be zero or positive. ![]() It is important to note that the vector PQ and the vector QP have the same magnitude but opposite directions, making them the negative vectors of each other. That is, QP is the negative vector for PQ, as depicted in the image below. Since these directions are opposite, we say that PQ = – QP. Vectors are only negative with respect to another vector.įor example, if a vector PQ points from left to right, then the vector QP will point from right to left. A negative sign will reverse the direction of a vector and make it a negative vector. Vectors having the same length as a particular vector but in the opposite direction are called negative vectors. In this article, we will discuss the following subtopics related to negative vectors: “A vector whose magnitude is the same as that of the reference vector, but its direction is opposite to that of the reference vector.” If there are negative scalars, is it also possible to have a negative vector? It is! In fact, a negative vector is: Negative Vectors – Explanation & Examples ![]() ![]() ![]() Urging that Martin be sanctioned for failing to answer questions and provide records in the case, the lawyers asked for a default judgment of $1,229,384.31.ĭemacopoulos signed an order granting that request on May 24. Less than a week later, the attorneys reported that $383,236.75 had been emptied from Wilkerson's accounts and that other people had to step in to cover the money that wasn't paid to his retirement home. The most recent transactions, from April 6 to April 28, totaled $2,875.29 and appeared to violate Demacopoulos' order, Wilkerson's attorneys wrote in urging the judge to order Martin to show why she shouldn't be held in contempt of court and ordered to return the money and show where it was moved. Then, through a subpoena, Wilkerson's lawyers obtained records showing that wire transfers of Wilkerson's money had been sent to accounts in a cryptocurrency exchange that also were emptied, according to a May 11 court filing. Less than a month later, the lawyers wrote, the former judge had "dissipated funds and may be engaging in risky crypto transactions that threaten the remaining funds that exist."Īt a hearing April 6, Demacopoulos ordered Martin "to refrain from transferring or using any further funds" from Wilkerson's accounts. In a filing last October, Wilkerson's lawyers voiced frustration about that and said they were taking their concerns to the Cook County state's attorney's office, the Illinois attorney general's office and the Illinois Department of Aging. Martin dodged questions and requests for information about the money as the litigation wore on, court records show. It says that's when he learned that his checking and investment accounts had been "emptied." And it was unclear where his Social Security and pension payments were being deposited. Martin later reported, in April 2022, that there was about $50,000 in Wilkerson's checking account and $120,000 in a retirement account, according to the suit.īut that July a red flag went up when Wilkerson got a notice saying he owed $41,296.10 to the senior home and that payments for him to live there hadn't been made in recent months, according to the suit. That was a month before Wilkerson moved to a seniors residence in Orland Park. Ellison, a friend of Wilkerson, was granted power of attorney as his health declined, according to the lawsuit, which says Ellison then tapped Martin to "supervise and manage" Wilkerson's financial affairs in November 2020. Bush.Īfter leaving the service, he delighted in taking children up for the first flights and worked at radio stations in Chicago and Harvey.ĭr. Wilkerson, who was the group's last known surviving member in the Chicago area, was among roughly 300 surviving members awarded the Congressional Gold Medal in 2007 by President George W. ![]() And, on May 24, Cook County Circuit Judge Anna Demacopoulos ordered Martin to pay Wilkerson's attorneys more than $1.2 million in damages, fees and court costs after Martin failed to answer questions about the money and to hand over records. ![]() Wilkerson sued Martin last September, saying she took advantage of him in his old age and hid his retirement money. Now, Martin is accused in a lawsuit of stealing more than $240,000 from Wilkerson's savings and retirement accounts, sinking more than $100,000 of it into cryptocurrency. lived a rich life, serving with the trailblazing Tuskegee Airmen during World War II before settling in Chicago's south suburbs and eventually being awarded the Congressional Gold Medal.Īs he grew old, his health deteriorated, and his finances were placed in the hands of Patricia Martin, a former presiding Cook County judge who's a niece of his former wife. Ex-Cook County Judge Patricia Martin must pay $1.2 million after allegedly stealing hundreds of thousands of dollars from a decorated Tuskegee Airman.ĬHICAGO - Oscar Wilkerson Jr. ![]() ![]() ![]() In contrast, a nitro substituent decreases the ring's reactivity by roughly a million. For example, a hydroxy or methoxy substituent increases the rate of electrophilic substitution about ten thousand fold, as illustrated by the case of anisole in the virtual demonstration (above). Experiments have shown that substituents on a benzene ring can influence reactivity in a profound manner. The first is the relative reactivity of the compound compared with benzene itself. When substituted benzene compounds undergo electrophilic substitution reactions of the kind discussed above, two related features must be considered: Thus, a sigma bond between sp 2- and sp 3‑carbon is slightly polarized, as follows: Note that one argument sometimes used to explain the ability of alkyl groups to donate electrons inductively to an aromatic ring is that sp 2‑hybridized carbon atoms are more electronegative than sp 3‑hybridized carbon atoms. Electrophilic addition to alkenes and electrophilic aromatic substitution are both polar, stepwise processes, and the key step for each is attack of an electrophile at carbon to form a cationic intermediate. If so, refer to Sections 2.1, 7.9 (paying particular attention to the “Study Notes”) and 14.5. You may wish to review earlier material on to the inductive effect. What you should be doing is trying to understand the factors that determine whether a given substituent will activate or deactivate a benzene ring with respect to electrophilic substitution. The answer is that if you are trying to memorize such things, you are taking the wrong approach to organic chemistry. On reading Objective 2 students may exclaim “How am I ever going to memorize all of this!”-or words to that effect. explain the resonance effects displayed by substituents such as nitro, carbonyl-containing, hydroxy, alkoxy and amino groups during electrophilic aromatic substitution reactions.explain the inductive effects displayed by substituents such as nitro, carboxyl, alkyl and the halogens during electrophilic aromatic substitution reactions.list a given series of aromatic compounds in order of increasing or decreasing reactivity with respect to electrophilic substitution.Arenes contain double bonds just like alkenes but they do not undergo electrophilic addition because these would result to their loss of ring aromaticity. explain, in general terms, the factors that determine whether a given substituent will activate or deactivate an aromatic ring with respect to electrophilic substitution. Aromatic compounds or arenes undergo substitution reactions, in which the aromatic hydrogen is replaced with an electrophile, hence their reactions proceed via electrophilic substitution.list a given series of substituents (selected from those given in Objective 2) in order of increasing or decreasing ability to activate or deactivate an aromatic ring with respect to electrophilic substitution. ![]() |
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